2. Brad Pitt and Angelina Jolie
If you thought that Gwyneth Paltrow was the only woman whom Brad Pitt had met on set let me prove you wrong! In 2004, while they were filming for the well-known action movie called “Mr. and Mrs. Smith”, the popular actor fell madly in love with his beautiful co-star, Angelina Jolie.
However, things were a bit complicated, because he was still married to one of America’s favorite actresses, Jennifer Aniston, who for 10 years played the role of Rachel Green from “F.R.I.E.N.D.S”.
Brad and his wife decided to end their marriage in 2005 and soon after that, he began a relationship with Angelina. By the time they went down the aisle in 2014, they were already the parents of six cute children.
It looks like fairytales aren’t meant to last forever, because in 2016 they decided to go their separate ways.